API-571 Exam Dumps - Corrosion and Materials Professional

Comprehensive and Detailed Explanation From Exact Extract:

According to API RP 571, graphitization is a high-temperature degradation mechanism that occurs in carbon and carbon-molybdenum steels exposed for long periods at temperatures typically above 800 °F (425 °C).

In this process:

Iron carbides decompose into free graphite nodules

The steel loses strength, ductility, and pressure-retaining capability

Failures can occur without significant wall loss

Graphitization does not occur in aluminum, stainless steels, or nickel-copper alloys such as Monel.

Referenced Documents (Study Basis):

API RP 571 – Section on Graphitization

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API RP 751, which governs HF alkylation units, specifies:

“The total residuals of chromium, nickel, and copper in carbon steel used in HF service should be less than 0.15 wt.% to minimize corrosion risk.”

“Higher residuals increase the reactivity and corrosion rate of carbon steel in the presence of HF acid.”

(Reference: API RP 751, Section 5.3 – Materials Specification for HF Units)

Therefore, option A is the correct choice.

API RP 571, under "Caustic Corrosion" (also referred to as Caustic Stress Corrosion Cracking or Caustic Cracking), notes that this form of damage is:

“Most commonly associated with the injection points of caustic (e.g., NaOH) in crude units, particularly upstream of desalter vessels and heat exchanger circuits.”

“This damage occurs due to the combination of caustic environment and tensile stress, especially in carbon steel and low alloy steels.”

“Stress relief heat treatment of welds can mitigate susceptibility.”

(Reference: API RP 571, 3rd Edition, Section 4.2.2.3)

Thus, among the options, caustic injections in crude units are the most typical area of concern, making option C the correct answer.

API RP 571 and RP 939-C define sulfidation conditions as:

“Sulfidation of iron-based alloys generally becomes significant at temperatures above 500°F (260°C) in hydrocarbon streams with sulfur but without hydrogen.”

“For hydrogen-containing environments, this threshold may be reduced to 450°F (230°C).”

(Reference: API RP 571, Section 4.2.1.1 – Sulfidation; API RP 939-C, Section 3.1)

Therefore, the correct answer is D.

According to API RP 571:

“Oxidation is the reaction of metal and oxygen to form oxides. It generally occurs in high temperature environments with excess oxygen.”

“Sulfidation is a high temperature corrosion mechanism that occurs due to interaction between sulfur-containing compounds and metal surfaces, forming metal sulfides. Like oxidation, sulfidation occurs in environments above 500 °F (260 °C).”

“Both oxidation and sulfidation can occur concurrently, particularly in mixed environments of oxygen and sulfur.”

(Reference: API RP 571, Sections 5.1.1 and 5.1.3 – Oxidation & Sulfidation)

These two mechanisms are thermally activated and occur in elevated temperature conditions found in heaters, furnaces, and piping systems. Hence, option B is correct.

In steam systems, the absence of a steam trap allows condensate to accumulate, which can lead to corrosion from oxygen and carbon dioxide dissolved in the water—a classic case of condensate corrosion.

From API RP 571 Section 5.3.3.1 (Condensate Corrosion):

“If steam lines or equipment like soot blowers do not have proper drainage or steam traps, condensate may accumulate... Corrosion results from the presence of dissolved oxygen and/or carbon dioxide in the condensate.”

Thus, the correct answer is Option D (condensate corrosion).

Same as above. Sigma phase formation is a microstructural phenomenon and not typically detected by NDE methods like magnetic particle or surface hardness testing.

Therefore, metallographic testing remains the definitive detection method, confirming option D again as the correct answer.

API RP 571 provides the following guidance regarding temper embrittlement:

“For materials that contain impurity levels which make them susceptible to temper embrittlement, the most effective preventive measure is to specify low FATT or Charpy impact energy requirements.”

“These requirements ensure the material retains adequate toughness even if embrittlement occurs.”

“While temper embrittlement itself cannot always be fully prevented during long-term exposure to temperatures between 650°F and 1070°F (343°C–577°C), its effects can be identified and mitigated through impact testing criteria.”

Therefore, option C is correct. Specification of Charpy V-notch testing ensures material selection accounts for embrittlement susceptibility and maintains service integrity.